全文获取类型
收费全文 | 5491篇 |
免费 | 867篇 |
国内免费 | 649篇 |
专业分类
化学 | 3919篇 |
晶体学 | 72篇 |
力学 | 329篇 |
综合类 | 47篇 |
数学 | 612篇 |
物理学 | 2028篇 |
出版年
2024年 | 4篇 |
2023年 | 114篇 |
2022年 | 95篇 |
2021年 | 154篇 |
2020年 | 208篇 |
2019年 | 164篇 |
2018年 | 174篇 |
2017年 | 154篇 |
2016年 | 253篇 |
2015年 | 231篇 |
2014年 | 319篇 |
2013年 | 350篇 |
2012年 | 468篇 |
2011年 | 515篇 |
2010年 | 384篇 |
2009年 | 342篇 |
2008年 | 370篇 |
2007年 | 361篇 |
2006年 | 317篇 |
2005年 | 277篇 |
2004年 | 213篇 |
2003年 | 150篇 |
2002年 | 164篇 |
2001年 | 131篇 |
2000年 | 106篇 |
1999年 | 126篇 |
1998年 | 106篇 |
1997年 | 99篇 |
1996年 | 96篇 |
1995年 | 73篇 |
1994年 | 84篇 |
1993年 | 55篇 |
1992年 | 63篇 |
1991年 | 56篇 |
1990年 | 38篇 |
1989年 | 54篇 |
1988年 | 37篇 |
1987年 | 35篇 |
1986年 | 15篇 |
1985年 | 14篇 |
1984年 | 9篇 |
1983年 | 8篇 |
1982年 | 5篇 |
1981年 | 8篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1971年 | 2篇 |
1959年 | 1篇 |
1957年 | 2篇 |
排序方式: 共有7007条查询结果,搜索用时 31 毫秒
991.
992.
In order to determine the role of laser in drought stress resistance of spring wheat (Triticum aestivum L.), seed embryos were exposed to CO2 laser radiation for 0min, 1min, 3min and 5min, respectively, and when the seedlings were 12 days old they were treated with 10% (w/v) PEG6000 solution for 10 days. Changes in the concentration of malondialdehyde (MDA), hydrogen peroxide (H2O2), glutathione (GSH), ascorbate (AsA), oxidized glutathione (GSSG), carotenoid, zeaxanthin, the production rate of superoxide radical (O2(-)), the activities of ascorbate peroxidase (APX), peroxidase (POD), catalase (CAT), superoxide dismutase (SOD), glutathione reductase (GR), glutathione peroxidase (GP), glutathione-S-transferase (GST) and the growth parameters of seedlings (plant height, leaf area and dry weight) were measured to test the effects of laser pretreatment. The results showed that suitable laser pretreatment of embryos enhanced drought stress resistance in wheat seedlings by decreasing the concentration of MDA and H2O2, GSSG, the production rate of O2(-), leaf area and increasing the activities of APX, GST, GP and POD and AsA, carotenoid and zeaxanthin concentration. It is suggested that those changes in MDA, O2(-) H2O2, anti-oxidative enzymes and anti-oxidative compounds were responsible for the increase in drought stress resistance observed in the experiments. The results also showed that the laser had a long-term positive physiological effect on the growth of drought stress seedlings. This is the first investigation reporting the use of CO2 laser pretreatment to enhance drought stress resistance of spring wheat. 相似文献
993.
本文利用含氢有机硅化合物与含双键的氨基酸酯的加成反应,合成了5种新的有机硅氨基酸衍生物。介绍了一种合成N-烷基取代氨基酸酯的新方法。对新化合物进行了元素和光谱分析鉴定。 相似文献
994.
穿过液膜的自发电势振荡 总被引:2,自引:0,他引:2
An artificial membrane consisting of pricramic acid in nitrobenzene was used as an oil phase imposed between two aqueous phases. The right one contained trimethyl-slearylammonium chloride and aicohol; and the left contained sucrose solution (or H_2O). We found that this system exhibited rhythmic oscillation of electrical potential. The amplitude of the oscillations was between 20—150 mV. The oscillations were observed even when ethyl alcohol was absent in the aqueous of trimethylslearylammonium Chloride, and the increase in amplitude of oscillation with time was found to be less in the presence of sucrose. Some of the expremental results have been explained. 相似文献
995.
以催化极谱法测定了54例白血病患者血清硒含量。结果表明,急淋、急粒患者血清硒含量均低于正常对照组,慢粒及急、慢粒经治疗缓解者血清硒含量与正常对照组间均无显著性差异,提示低硒状态只存在于急性患者,且随病情缓解后血硒水平趋于正常,慢粒与血硒含量没有明显的相关关系。 相似文献
996.
Tetrathiafulvalene (TTF) is trapped inside a dimeric capsule formed by two octaacid, deep-cavity cavitands in aqueous solution. While the first one-electron oxidation of TTF is strongly hindered by encapsulation, the capsular assembly is eventually destabilized upon oxidation of the guest. 相似文献
997.
高硅沸石骨架结构及其稳定性的模拟计算(I)* 总被引:2,自引:0,他引:2
The lattice energy of a series of high-silica zeolites was determined using the lattice energy minimization method. The results were compared to the lattice energy of dense polymorphs of SiO2. All high-silica zeolites frameworks are only 30~67kJ•mol-1 less stable than α-quartz This may imply that there is little energy barrier to the formation of high-silica zeolites frame-works and explain the structural diversity observed for high-silica zeolites. The relationships of calculated lattice energies and framework Structures was disscussed. The results revealed a good linear relationship between framework density of these molecular sieves and all-silica framework lattice energies. 相似文献
998.
自由基活性聚合及其最新进展 总被引:5,自引:2,他引:5
本文介绍了实现自由基活性聚合的动力学、热力学条件及可能的途径。在这些条件下自由基保持稳定的低浓度,增长链自由基与休眠种处于动力学平衡动态,可有效地控制聚合反应,使聚合反应具有聚合物分子量随反应时间、单体转化率成线性增长关系及所得聚合物分子量分布较窄的特征,并且在加入第二单体时可继续生成嵌段共聚物。 相似文献
999.
1000.
We investigate the shape deformation of an infinite membrane anchored by a rigid rod. The density profile of the rod is calculated by the self-consistent-field theory and the shape of the membrane is predicted by the Helfrich membrane elasticity theory [W. Helfrich, Z. Naturforsch. 28c, 693 (1973)]. It is found that the membrane bends away from the rigid rod when the interaction between the rod and the membrane is repulsive or weakly attractive (adsorption). However, the pulled height of the membrane at first increases and then decreases with the increase of the adsorption strength. Compared to a Gaussian chain with the same length, the rigid rod covers much larger area of the membrane, whereas exerts less local entropic pressure on the membrane. An evident gap is found between the membrane and the rigid rod because the membrane's curvature has to be continuous. These behaviors are compared with that of the flexible-polymer-anchored membranes studied by previous Monte Carlo simulations and theoretical analysis. It is straightforward to extend this method to more complicated and real biological systems, such as infinite membrane/multiple chains, protein inclusion, or systems with phase separation. 相似文献